Porous liquids combine permanent nanoscale cavities with fluidity, making them promising for applications like carbon dioxide capture, gas separation and other chemical processes. Their viscosity must be tailored to the intended application: Lower-viscosity liquids are easier to pump and circulate while facilitating faster heat and mass transfer, whereas higher-viscosity liquids provide greater structural stability in membrane formation.
Just a few atomic layers at the surface can strongly influence how effectively a material binds pollutants from water or how efficiently a photocatalyst responds to light. Researchers at the Fraunhofer Institute for Applied Polymer Research IAP use X-ray photoelectron spectroscopy (XPS) to investigate the chemical states and interactions at the surfaces and interfaces of bio-based carbon materials and organic-inorganic hybrid materials. Their insights can support the targeted development of functional materials for future industrial applications.
Researchers at University of Tsukuba have discovered that the crystal structure of zirconia nanoparticles remains stable under uniform pressure applied from all directions but changes under anisotropic pressure. This unique property is expected to lead to new technologies for detecting and evaluating pressure anisotropy, which has been difficult to assess using conventional methods.
Researchers from the Singapore-MIT Alliance for Research & Technology's (SMART) Antimicrobial Resistance (AMR) interdisciplinary research group, alongside collaborators from Massachusetts Institute of Technology (MIT), Nanyang Technological University (NTU Singapore), and institutions in the United States, Poland and France, have discovered aminovaleramididine synthetase (AvaS), the first identified pyridoxal phosphate (PLP)-dependent enzyme responsible for producing a chemical modification linked to how bacteria respond to metabolic stress.
Anna Sheinberg, Ph.D. candidate in chemistry, is working with fellow researchers in Trinity College's Chemistry Department and at the Nasher Museum of Art to uncover new information about some of the ancient dyed textiles in the Nasher's collection.
Imagine this. You pick up a contact lens from its container and—yikes!—it falls on the bathroom floor. Before you know it, your cat pounces, claws out. By the time you wrestle it back, the lens looks like a tiny chew toy. And then, just like that—the scratches fade away and the ripped edge seals itself up.
Life in the deep sea is under immense pressure—literally. Such extreme conditions can disrupt the delicate structures of proteins essential to life. Yet somehow, the proteins in deep-sea creatures remain functional. This raises an intriguing question: how?
For more than a century, pharmaceutical companies have relied on flat structures called aromatic rings, which can help drugs bind to target sites in the body. They include benzene rings and other flat, nitrogen-containing rings. But there are limits to their usefulness.
Your favorite pair of tennies, kicks or trainers may soon become a little more sustainable. In a study published Sept. 11 in the journal Chem Catalysis, researchers developed a new kind of enzyme based on a bacterium found in compost that can degrade the polyurethane material in shoe foams. The results could one day help recycle plastic waste from shoes, mattresses, kitchen sponges and more.
Fluorinated waste, like that found in firefighting aqueous film-forming foam, can act as a significant environmental pollutant. Recently, James Tour's lab at Rice University developed a method to capture fluoride from these waste streams and recycle it into a useful reagent, silver fluoride, that could be used in other manufacturing processes. This process is published in Nature Chemical Engineering.
While chemical bonds usually determine the structure and properties of a material, bonds between neighboring metal atoms can also change as temperature or other conditions change. These changes can lead to unusual electronic and magnetic behaviors.
Researchers from Aarhus University and the Danish Technological Institute have taken a new approach in the search for enzymes capable of breaking down some of the most difficult types of plastic to recycle. They collected millions of bacteria from a landfill in Kenya, Randers Regnskov Tropical Zoo, the guts of larvae and a compost heap near Aarhus—and examined their enzymes. They found 12 that work.
Packaging already tells us where food comes from, when it was made, what's in it and how many calories it contains. But researchers see a future where packaging can "see," in real time, what's happening inside and translate that into information that producers and consumers can act on.
RhoBAST is a tiny RNA molecule that activates fluorescent dyes, enabling researchers to track RNA molecules in living cells with super-resolution. An international collaboration, which includes Ronald Micura and his team from the Institute of Organic Chemistry, has now shown that a small, local "nucleotide flip" within the RNA controls this fluorescence activation.
Hydrogen (H2) evolution via photocatalytic water splitting is an environmentally friendly and sustainable technology for solar-to-chemical energy conversion. Although interfacial interactions are recognized as key determinants of photocatalytic performance, systematic experimental studies explicitly targeting the structure and reactivity of the water-catalyst interface remain limited. A major challenge lies in probing the molecular structure of interfacial water, especially under hydrogen-evolving conditions.
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